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991.
The present study describes the potential of the synchrotron radiation based X-ray fluorescence spectroscopy technique for the rapid, sensitive, user friendly and simultaneous monitoring of the changes in the elemental profile of the wheat seedlings stressed by excess manganese (Mn). For this, X-ray fluorescence spectra of the leaves of the control and Mn treated wheat seedlings have been recorded by synchrotron radiation X-ray of energy 15?keV. The analyses of the recorded spectra show the presence of elements chlorine, potassium, calcium, manganese, iron, copper, nickel, and zinc. A calibration-free approach, PyMca has been used for the quantitative estimation of the detected elements in the leaves of the control and Mn treated wheat seedlings. The excess supply of Mn to wheat seedlings results in the accumulation of manganese in the leaves of the seedlings. The accumulation of manganese in wheat seedlings negatively affects the uptake and translocation of calcium, potassium, and iron while it has stimulating effect on the uptake of copper and zinc. 相似文献
992.
993.
Simulations of X‐ray diffraction of shock‐compressed single‐crystal tantalum with synchrotron undulator sources 下载免费PDF全文
Polychromatic synchrotron undulator X‐ray sources are useful for ultrafast single‐crystal diffraction under shock compression. Here, simulations of X‐ray diffraction of shock‐compressed single‐crystal tantalum with realistic undulator sources are reported, based on large‐scale molecular dynamics simulations. Purely elastic deformation, elastic–plastic two‐wave structure, and severe plastic deformation under different impact velocities are explored, as well as an edge release case. Transmission‐mode diffraction simulations consider crystallographic orientation, loading direction, incident beam direction, X‐ray spectrum bandwidth and realistic detector size. Diffraction patterns and reciprocal space nodes are obtained from atomic configurations for different loading (elastic and plastic) and detection conditions, and interpretation of the diffraction patterns is discussed. 相似文献
994.
本研究利用低温间质隔离技术搭配红外光谱仪研究CH3ONO在p-H2间质中的光解产生CH3O。实验观察到位于689.3/694.6cm-1、945.9/951.7cm-1、1041.8cm-1、1224.7cm-1、1235.5cm-1、1347.7cm-1、1365.4cm-1、1427.5cm-1、1519.5cm-1、1522.3cm-1等处的CH3O红外吸收谱线,并分析得出各振动模式分别为电子态E1/2a1对称性的ν6、电子态E1/2a2对称性的ν6、电子态E3/2对称性的ν2、电子态E3/2e对称性的ν6、电子态E1/2e对称性的ν6、电子态E1/2a1对称性的ν5、电子态E3/2对称性的ν2、电子态E1/2对称性的ν2、电子态E3/2e对称性的ν5及电子态E1/2e对称性的ν5。 相似文献
995.
选择含能聚合物聚叠氮缩水甘油醚(GAP)作为激光烧蚀微推力器的工质,分析了红外染料掺杂对激光烧蚀GAP工质推进性能的影响.通过对比掺杂红外染料GAP在不同激光功率密度、掺杂浓度、靶材厚度和激光烧蚀模式下的推进性能数据和烧蚀羽流,初步探索了掺杂红外染料GAP工质的推进性能优化方式.实验结果表明:透射式激光烧蚀模式下,激光能量的指数衰减特性和掺杂红外染料GAP的强黏性使得烧蚀羽流中易存在未充分烧蚀的工质; GAP的推进性能受红外染料掺杂浓度和靶材厚度的综合影响,当靶材厚度与激光吸收深度接近时,靶材充分吸收激光能量使中心烧蚀区达到化学能释放的温度阈值,同时沿激光传播方向未充分烧蚀的质量最少,此时推进性能达到最优值.反射式下掺杂红外染料的聚合物的激光烧蚀过程遵循"先吸收激光能量先喷射"的规律,工质分解充分,推进性能优于透射式. 相似文献
996.
P. R. T. Munro 《Contemporary Physics》2017,58(2):140-159
Contemporary X-ray imaging techniques span a uniquely wide range of spatial resolutions, covering five orders of magnitude. The evolution of X-ray sources, from the earliest laboratory sources through to highly brilliant and coherent free-electron lasers, has been key to the development of these imaging techniques. This review surveys the predominant coherent X-ray imaging techniques with fields of view ranging from that of entire biological organs, down to that of biomolecules. We introduce the fundamental principles necessary to understand the image formation for each technique as well as briefly reviewing coherent X-ray source development. We present example images acquired using a selection of techniques, by leaders in the field. 相似文献
997.
The high-resolution Fourier transform infrared spectrum of CH2D79Br has been recorded and analysed in the region of the ν4 and ν8 fundamentals located in the range 1125?1360 cm?1. The strong ν4 band, centred at 1225 cm?1, shows an a/b-hybrid structure with predominant a-type character, whereas ν8, at 1253 cm?1, generates a c-type contour comparable in intensity to the b-type component of ν4. The upper states of these fundamentals are coupled through a- and b-type Coriolis resonances; further complications in this band system arise from perturbations due to the ν6 = 2 (1183 cm?1) and ν5 = ν6 = 1 (1359 cm?1) dark states. The former interacts with ν8 = 1 by b-type Coriolis coupling, whereas the latter perturbs the ν4 = 1 and ν8 = 1 levels by anharmonic and a-type Coriolis resonances, respectively. Accurate upper state parameters and interaction terms have been determined for the tetrad system ν4/ν8/2ν6/ν5+ν6 by also including in the dataset the assigned transitions of the 2ν6?ν6 and ν5+ν6?ν6 hot bands obtained from previous analysis. 相似文献
998.
Anomalous behavior and phase transformation of α-GaOOH nanocrystals under static compression 下载免费PDF全文
The structural compression mechanism and compressibility of gallium oxyhydroxide, α-GaOOH, are investigated by in situ synchrotron radiation x-ray diffraction at pressures up to 31.0 GPa by using the diamond anvil cell technique. Theα-GaOOH sustains its orthorhombic structure when the pressure is lower than 23.8 GPa. The compression is anisotropic under hydrostatic conditions, with the a-axis being most compressible. The compression proceeds mainly by shrinkage of the void channels formed by the coordination GaO_3(OH)_3 octahedra of the crystal structure. Anomaly is found in the compression behavior to occur at 14.6GPa, which is concomitant with the equatorial distortion of the GaO_3(OH)_3 octahedra. A kink occurs at 14.6 GPa in the plot of finite strain f versus normalized stress F, indicating the change in the bulk compression behavior. The fittings of a second order Birch–Murnaghan equation of state to the P–V data in different pressure ranges result in the bulk moduli B_0= 199(1) GPa for P 14.6 GPa and B_0= 167(2) GPa for P 14.6 GPa. As the pressure is increased to about 25.8 GPa, a first-order phase transformation takes place, which is evidenced by the abrupt decrease in the unit cell volume and b and c lattice parameters. 相似文献
999.
为了解决个人隐私的保护、受光照条件和障碍物等因素的影响,设计了一种基于屋顶二值红外传感器网络的人体行为识别系统。系统采用STM32芯片和ZigBee协调器建立ZigBee网络。当实验者在安装在屋顶的20个互连的AMN31111红外传感器下面做出一系列行为时,传感器对其进行二值数据采集,ZigBee协调器将数据通过串口发送到PC机上实时动态显示,通过Keil 5系统软件对采集的二值数据以txt文本格式存储。提出了像素值法对人体进行定位和BP神经网络算法在模拟的居家环境中对7种不同人物行为进行识别。实验结果表明:该系统实现了人体多种行为的识别,其识别率为84.7%,4名实验者得到平均识别精度相比固定在居家电器传感器设备要高4.7%左右,并且该系统采集精度高、性能稳定、可靠性高、成本低、功耗低,解决了一些目前人体行为识别监测系统存在的问题。 相似文献
1000.